PUBLICATIONS
2022
35. “Hydrogen tunneling in Catalytic Hydrolysis and Alcoholysis of Silanes” N. Almenara, M. A. Garralda, X. López, J. M. Mataxain, Z. Freixa, M. A. Huertos* Angew. Chem. Int. Ed. 2022, 61, e202204558.
2021
34. "Oxidative addition of secondary phosphine oxides through Rh(I) center: hydrido-phosphinito-Rh(III) complexes and their catalytic activity in hydrophosphinylation of alkynes" N. Almenara, M. Barquin, M. A. Huertos*, M. A. Garralda* Eur. J. Inorg. Chem. 2021, 4938-4945.
33. "Experimental and DFT studies on hexacoordinatedacyl (alkyl)and pentacoordinated hydroxyalkyl (phosphinite)rhodium(III)). Catalytic hydrolysis of ammonia-borane". S. Azpeitia, C. Mendicute-Fierro, M. A. Huertos, A. Rodriguez-Dieguez, J. M. Seco, A. J. Mota, M. A. Garralda*, Eur. J. Inorg. Chem, 2021, 879-891
32. "Steric Effects in the catalytic tandem isomerization-hydrosilylation reaction" U. Prieto, S. Azpeitia, E. San Sebastián, Z. Freixa, M. A. Garralda, M. A. Huertos*, ChemCatChem, 2021, 13, 1403-1409
2020
31. "Si–C(sp3) bond activation throgh oxidative addition at a Rh(I) centre" S. Azpeitia, A. J. Martinez-Martinez, M. A. Garralda, A. S. Weller,* M. A. Huertos*, Dalton Trans., 2020, 49, 5416-5419. (Hot Article)
2019
30. "A phosphine-stabilized silylene rhodium complex" N. Almenara, J. I. Miranda, A. Rodríguez-Diéguez, M. A. Garralda, M. A. Huertos*, Dalton Trans., 2019, 48, 3300-3313.
29. "(Diphenylphosphine)alkylaldehyde to afford hydride- or alkyl-[(diphenylphosphine)alkylacyl]rhodium(III) or (diphenylphosphine)alkylester complexes. Theoretical and experimental diastereoselectivity." S. Azpeitia, M. Barquin, C. Mendicute-Fierro, M. A. Huertos, A. Rodríguez-Diéguez, J. M. Seco, E. San Sebastián, L. Ibarlucea, M. A. Garralda*, Dalton Trans., 2019, 48, 3300-3313.
2018
28. "Rh(III)-Catalysed Solvent-Free Hydrodehalogenation of Alkyl Halides by Tertiary Silanes" N. Almenara, S. Azpeitia, M. A. Garralda, M. A. Huertos*, Dalton Trans., 2018, 47, 16225-16231.
27. "Alkene-Alkyl Interconvension: An Experimental and Computational Study of the Olefin Insertion and beta-Hydride Elimination Processes" S. Azpeitia, U. Prieto, E. San Sebastián, A. Rodriguez-Dieguez, M. A. Garralda, M. A. Huertos*, Dalton Trans., 2018, 47, 6808-6818.
26. "From Remote Alkenes to Linear Silanes or Allylsilanes Depending on the Metal Center" S. Azpeitia, A. Rodriguez-Dieguez, M. A. Garralda, M. A. Huertos* , ChemCatChem, 2018, 10, 2210-2213.
2017
25. "Ion-macromolecule interactions studied with model polyurethanes" Borja Fernádez-d'Arlas, M. A. Huertos, Alejandro J. Müller, JCIS, 2017, 509, 102-112.
24. "Rhodium(III) Catalysed Solvent-Free Tandem Isomerization-Hydrosilylation From Internal Alkenes to Linear Silanes" S. Azpeitia, M. A. Garralda, M. A. Huertos* , ChemCatChem, 2017, 9, 1901-1905.
2016
23. "A Pentacoordinated Norbornenyl-Acyl-R(III) Complex as a Likely Intermediate in the Catalytic Hydroacylation of Norbornadiene" N. Almenara, L. Ibarlucea, C. Mendicute-Fierro, J. M. Seco, A. Rodriguez-Dieguez, M. A. Garralda, M. A. Huertos*, Dalton Trans. 2016, 54, 18502-18509.
22. “Activation of Aromatic C–C Donds of 2,2’-Bipyridine Ligands” S. Fombona, M. Espinal-Viguri, M. A. Huertos, J. Diaz, R. López, M. I. Menéndez, J. Pérez, L. Riera, Chem. Eur. J. 2016, 22, 17160-17164.
21. “Irida-β-ketoimines Derived from Hydrazines To Afford Metallapyrazoles or N-N Bond Cleavage: A Missing Metallacycle Disclosed by a Theoretical and Experimental Study.” I. Zumeta, C. Mendicute-Fierro, I. Bustos, M. A. Huertos, A. Rodriguez-Dieguez, J. M. Seco, E. San Sebastián, M. A. Garralda.,Inorg. Chem. 2016, 55, 10284-10293.
20. “Dehydrogenative Coupling of a Tertiary Silane Using Wilkinson's Catalyst” S. Azpeitia, B. Fernandez, M. A. Garralda, M. A. Huertos*, Eur. J. Inorg. Chem. 2016, 2891-2895. (Cover Picture)
2015
19. “Silyl-Thioether Multidentate Ligands: Synthesis of Rh(III) Compounds via Rh(I)/Rh(III) Mixed Valent and Cyclooctenyl Intermediates” S. Azpeitia, B. Fernandez, M. A Garralda, M. A. Huertos*. Eur. J. Inorg. Chem. 2015, 5451-5456
PRE- AND POSTDOCTORAL
18. “Air-Stable Gold Nanoparticles Ligated by Secondary Phosphine Oxides as Catalyst for the Chemioselective Hydrogenation of Substituited Aldehydes: a Remarkable Ligand Effect” I. Cano, M. A. Huertos, A. M. Chapman, G. Bumtkowsky, T. Gutmann, P. B. Groszewicz, P. W. N. M. van Leeuwen. J. Am. Chem. Soc. 2015, 137, 7718-7727.
17. “Phosphinothiolates as Ligands for Polyhydro Copper Nanoclusters” M. A. Huertos, I. Cano, N. A. G. Bandeira, J. Benet-Buchholz, C. Bo, P. W. N. M. van Leeuwen. Chem. Eur. J. 2014, 20, 16121-16127. (Cover Picture)
16. “Effect of the Phosphine Steric and Electronic Profile on the Rh–Promoted Dehydrocoupling of Phosphine-Boranes” T. N. Hooper, M. A. Huertos, T. Jurca, S. D. Pike, A. S. Weller, I. Manners, Inorg. Chem. 2014, 53, 3716-3729.
15. “Imidazole-Nitrile or Imidazole-Isonitrile C-C Coupling on Rhenium Tricarbonyl Complexe” M. E. Viguri, M. A. Huertos, J. Perez, L. Riera. Chem. Eur. J. 2013, 19, 12974-12977.
14. “Bis(phosphine)boronium salts. Synthesis, structures and coordination chemistry” T. A. Shuttleworth, M. A. Huertos, I, Pernik, R. D. Young, A. S. Weller, Dalton Trans. 2013, 42, 12917-12925.
13. “Revealing the P-B coupling event in the rhodium catalysed dehydrocoupling of phosphine-boranes H3B·PR2H (R = tBu, Ph)” M. A. Huertos, A. S. Weller. Chem. Sci. 2013, 4, 1881-1888.
12. “Dehydrocoupling of Dimethylamine Borane Catalysed by Rh(PCy3)2H2Cl” L. J. Sewell, M. A. Huertos, M. E. Dickinson, A. S. Weller, G. C. Lloyd-Jones. Inorg. Chem. 2013, 52, 4509-4516.
11. “Re-Mediated C−C Coupling of Pyridines and Imidazoles” M. E. Vigury, M. A. Huertos, J. Pérez, L. Riera, I. Ara. J. Am. Chem. Soc. 2012, 132, 20326-203329.
10. “Intermolecular Alkyne Hydroacylation. Mechanistic Insight from the Isolation of the Vinyl Intermediate that Precedes Reductive Elimination “ R. Pawley, M. A. Huertos, G. Lloyd-Jones, A. S. Weller, M. C. Willis. Organometallics, 2012, 31, 5650-5659.
9. “Double Activation of an N-Alkylimidazol “ M. A. Huertos, J. Pérez, L. Riera. Chem. Eur. J. 2012, 18, 9530-9533.
8. “Intermediates in the Rh-catalysed dehydrocoupling of Phosphine-Borane” M. A. Huertos, A. S. Weller. Chem. Commun . 2012, 48, 7185-7187.
7. “Imidazole to NHC Rearragements at Molibdenum denters: An Experimental and Theorical Study” ” M. Brill, M. A. Huertos, J. Pérez, L. Riera, J. Díaz, R. López. Chem. Eur. J. 2011, 17, 8584-8595.
6. “Organometallic Complexes with Terminal Imidazolato Ligands and their Use as Matalloligands” E. Gómez, M. A. Huertos, J. Pérez, L. Riera, A. Menéndez-Velázquez. Inorg. Chem. 2010, 49, 9527-9534.
5. “From Bis(N-Alkylimidazole) to Bis(NH-NHC) Complexes: A New Reactivity Pattern in Rhenium Carbonyl Complexes” M. A. Huertos, J. Pérez, L. Riera, J. Díaz, R. López. Angew. Chem. Int. Ed., 2010, 49, 6409-6412.
4. “Influence of the substituent in N-alkylimidazole ligands at a rhenium center: Ring opening vs. NHC complex formation” M. A. Huertos, J. Pérez, L. Riera, J. Díaz, R. López. Chem. Eur. J. 2010, 16, 8495-8507.
3. “From N-alkylimidazole ligands at a rhenium center: ring-opening or formation of NHC complexes” M. A. Huertos, J. Pérez, L. Riera, A. Menéndez-Velázquez. J. Am. Chem. Soc. 2008,130, 13530-13531.
2. “Pyridine ring opening at room temperature at a rhenium tricarbonyl bipyridine complex” M. A. Huertos, J. Pérez, L. Riera. J. Am. Chem. Soc. 2008, 130, 5662-5663.
1. “Synthesis, structure and reactivity of mononuclear Re(I) oximato complexes” L. Cuesta, M. A. Huertos, D. Morales, J. Pérez, L. Riera, V. Riera, D. Miguel, A. Menéndez-Velázquez, S. García-Granda. Inorg. Chem. 2007, 46, 2836-2845.
REVIEWS
1. “Dearomatization of Transition Metal-Coordinated N-Heterocyclic Ligands and Related Chemistry” R. Arevalo, M. Espinal-Viguri, M. A. Huertos, J. Perez, L. Riera. Adv. Organomet. Chem. 2016, 65, 47-114.
